Pengaruh Variasi Temperatur Terhadap Sifat Hidrofobik Komposit PDMS-Silika Sekam Padi-Graphene Oxide

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Rahmi Hendrika Putri
Ratnawulan

Abstract

Polydimethylsiloxane (PDMS)-based electrical insulators are widely used in outdoor power systems due to their inherent hydrophobic properties. However, the hydrophobicity of pure PDMS tends to diminish upon prolonged exposure to heat. This study aims to investigate the effect of varying heat treatment temperatures on the hydrophobicity of PDMS composites reinforced with silica derived from rice husk ash and graphene oxide, using contact angle measurements. The composites were fabricated via spin coating onto glass substrates and subsequently heated at five different temperatures—25 °C, 50 °C, 75 °C, 100 °C, and 125 °C—for one hour. Contact angles were measured using the sessile drop method and ImageJ software. The results indicate that the contact angle increased progressively with temperature, rising from 101.9° at 25 °C to a peak of 107.7° at 100 °C, before decreasing to 100.2° at 125 °C due to thermal degradation. All samples across the tested temperature range remained hydrophobic (θ > 90°), with 100 °C identified as the optimum temperature.

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Ariati, R., Sales, F., Souza, A., Lima, R. A., & Ribeiro, J. (2021). Polydimethylsiloxane composites characterization and its applications: A review. Journal Polymers, 13(23), 1–21.

Emiliah. (2025). Pengaruh variasi konsentrasi silika dari sekam padi pada lembaran PDMS terhadap sifat hidrofobik dan resistansi isolator listrik. Skripsi, Universitas Negeri Padang.

Ferbi, A., Arief, J., & Hakim, R. (2016). Pengaruh temperatur perlakuan panas pada lapisan hydrophobic komposit PDMS/SiO2. Jurnal Sains dan Seni ITS, 5(1), 1–5.

Han, R., Li, Y., Zhu, Q., & Niu, K. (2022). Research on the preparation and thermal stability of silicone rubber composites: A review. Composites Part C, 8, 100249.

Maguga, S. (2023). Pengaruh difusi air terhadap dielektrik dan hidrofobik pada material elastomer silikon. Accident Analysis and Prevention, 183(2), 153–164.

Nehan, P. Z. Z., Akbar, A. A., Karim, M. I. N., Fahriza, R. A., & Zainuri, M. (2023). Synthesis of silica from rice husk waste for hydrophobic material as an anti-water coating for eyeglasses. Jurnal Fisika dan Aplikasinya, 19(2), 44.

Ning, K., Lu, J., Jiang, Z., Xie, P., Feng, T., Hu, J., Fu, Z., & Tang, Z. (2023). Aging characteristics and lifespan prediction for composite insulator silicone rubber in a mountainous region environment. Polymer Testing, 122, 108023.

Putri, T. A., et al. (2018). Sintesis lapisan hydrophobic nanokomposit mangan oksida/polystyrene (MnO2/PS) untuk aplikasi self cleaning. Journal Pillar of Physics, 11(2), 1–8.

Sethi, S. K., & Manik, G. (2018). Recent progress in super hydrophobic/hydrophilic self-cleaning surfaces for various industrial applications: A review. Polymer-Plastics Technology and Engineering, 0(0), 1–21.

Wente, Himma, N. F., & Sofiatun Anisah, N. P. (2015). Membran superhidrofobik. Diktat Departemen Teknik Kimia Institut Teknologi Bandung.

Zeng, Q. (2021). Nanoscale review on the recent development of durable superhydrophobic materials for practical applications. The Royal Society of Chemistry, 11734–11764.